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Present and past areas of research: Development of new synthetic methods (umpolung of reactivity, use of organometallic derivatives, of aliphatic nitro-compounds, of small rings, and of tartaric acid, enantioselective catalysis, self-regeneration of stereogenic centers, use of microorganisms and enzymes, chiral fluorine-containing building blocks, backbone modifications of peptides), natural product synthesis (macrodiolides, alkaloides, amino acids), mechanistic studies (dissociation of C,C bonds, stability of carbenoids, aggregation of Li-compounds, pyramidalization of trigonal centers, TiX4 catalysis), structure determination (Li- and Mg-derivatives, NMR-spectroscopy, X-ray diffraction), chemical and biochemical aspects of poly(hydroxyalkanoates)(PHB/PHA), syntheses of enantiopure compounds with TADDOL auxiliaries, chiral dendrimers, and β-peptides, the latter area being the topic of present research, together with mechanistic investigations of organocatalyses.
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CHEMISTRY & BIODIVERSITYno. 10 (2018)
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