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Sullivan continued to pursue his interests in the development and application of photoexcited states of polypyridyl complexes of ruthenium, osmium, and rhenium. This work included developing chemical sensor applications and probing the molecular environment within thin films and similar structures, as well as continued development of photochemical energy conversion systems.
In recent years, Sullivan's research group developed novel linear oligomeric diphosphine-bridged complexes of rhenium(I), explored the coordination and electronic properties of new carboranyl phosphine ligands, and devised synthetic routes to coordination-complex-based molecular squares and arrays.
Most recently, in collaboration with workers at Pacific Northwest National Laboratory, Sullivan reported new highly oxidizing excited states of rhenium and technetium that formed the basis for the Department of Energy-funded research that he was conducting at the time of his death. He joined ACS in 1979.
In recent years, Sullivan's research group developed novel linear oligomeric diphosphine-bridged complexes of rhenium(I), explored the coordination and electronic properties of new carboranyl phosphine ligands, and devised synthetic routes to coordination-complex-based molecular squares and arrays.
Most recently, in collaboration with workers at Pacific Northwest National Laboratory, Sullivan reported new highly oxidizing excited states of rhenium and technetium that formed the basis for the Department of Energy-funded research that he was conducting at the time of his death. He joined ACS in 1979.
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Topics in Current Chemistry-Series (2007): 45-100
mag(2007)
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