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During his career, Johnson has conducted extensive research into many different areas of chemistry. He had a long running research partnership with Jack Lewis, with whom he discovered a number of unusual metal carbonyl clusters
Distinguished for his contributions to transition metal chemistry. His early work was concerned with the chemistry of nitrosyl complexes and the reactivity of the coordinated nitric oxide group. Subsequent work was concerned with the structure and reactivity of simple organic molecules coordinated to a metal centre, particularly those containing unsaturated carbon centres. The emphasis of his more recent work has been in the field of polynuclear carbonyl complexes particularly in Ruthenium and Osmium. A wide range of new bonding modes for both metal and ligand groups have been identified and the general stereochemical properties of the metal polyhedron have been rationalised in terms of a model depending upon the packing of the coordinated carbonyl groups. This model has been extended to account for the fluxionality observed in these complexes. Johnson has been responsible, in part, for the rapid development of cluster chemistry and the recognition of the difference in the properties of these complexes from mononuclear species
Distinguished for his contributions to transition metal chemistry. His early work was concerned with the chemistry of nitrosyl complexes and the reactivity of the coordinated nitric oxide group. Subsequent work was concerned with the structure and reactivity of simple organic molecules coordinated to a metal centre, particularly those containing unsaturated carbon centres. The emphasis of his more recent work has been in the field of polynuclear carbonyl complexes particularly in Ruthenium and Osmium. A wide range of new bonding modes for both metal and ligand groups have been identified and the general stereochemical properties of the metal polyhedron have been rationalised in terms of a model depending upon the packing of the coordinated carbonyl groups. This model has been extended to account for the fluxionality observed in these complexes. Johnson has been responsible, in part, for the rapid development of cluster chemistry and the recognition of the difference in the properties of these complexes from mononuclear species
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Stepfanie Vanekklapp, Joseph Guercio, Tyler Schwartz, Jessica Cornellier,Brian F G Johnson, Chris Lewis, Jim Engelkes, Erika Reck, David Howe, Kris Denolf
mag(2015)
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